Eps 24 at about 18:40 has a pan of all the captains, no numbers though, but you can get a general idea. The set up is similar to this (its kinda rough, but you can figure it out):

......1
2.......
4........
6........5
8........7
10......9
12......11

...(3)(The pan is from Gin's perspective so he isn't in the shot.)
[13th squad captain is not present.]

{The match ups are made from Lunar eps 24, 18:46, bottom of the chart is the closest to the screen}
The names excepting Gin's and a few others could possibly be considered spoilers, so you're on your own for that unless you use the spoiler link (My First Warning to you that it contains spoilers) below.


Don't go to this link if you don't want any spoilers of any kind, but Bleach7 has a full (or close enough) listing of captains and vice captians.
This link has spoilers based off the manga
http://bleach7.com/index.php?page=in...hcaptainsguide

One final warning: It contains quite a few huge spoilers so go there with caution! It is based off the manga.

I warned you more than enough times, so don't start flaming about getting me banned if you didn't want to see some of the spoilers in the descriptions but went there anyway.