If you want the original story skip to 110-127 thats where the anime picks up with the actual aftermath of the SS Arc. Then skip to 138-present. If all you care about is specifically seeing certain captains again then either skip to 92-109 where the filler arc moves to SS or just pick up the manga. It sounds like you just want captain level action, for that the main story should provide enough to entertain you for a while, in the end the show isn't about SS Captains it's about Ichigo and his friends and the people they fight.