Fine, if that's how you want to play itOriginally Posted by Assertn
Supa Supa no Mi - The fruit eaten by Mr. 1 that allows him to turn his body to steel. As far as i know, steel can't be found in nature and must be created by man
Bomu Bomu no Mi - The fruit eaten by Mr. 5 that allows him to become a human bomb, another human creation ( although i guess you could make the point that nature could combine its elements to create a bomb aswell even without human interference )
Shari Shari no Mi - A fruit eaten my a marine officer that allows him to turn him arms and feet into wheels, perhaps one of humanity's first creations
This is an interesting fruit since it was introduced in the manga during the Enies Lobby escape but was never shown in the anime. Since the event has already happened, i wouldn't call this a spoiler.
Details here - http://onepiece.wikia.com/wiki/Shari_Shari_no_Mi