There's no merchant that travels to Country X expecting the customers to pay in Country Y's currency, while all the time knowing full well Country X doesn't officially use that particular currency. Maybe that currency would exist in that country to some degree, maybe it wouldn't, but why would they specifically count on it? The only exception is if it was beforehand agreed that they would be paid in that currency. Like oil has been typically traded in dollars in our world. However, if that was the case, why did this whole incident happen? Rimuru would have known beforehand they need to have a lot of dwarven coin, so he would have arranged to have it ready and waiting. From this we know the foreign merchants most definitely were not promised dwarven coins when they were invited in.
Sure, technically those goons probably were merchants in their original countries, but they ceased to be merchants and became disposaple agents the moment they agreed to work for the mafia. They probably were promised some kind of big reward for it, in addition to any normal profit they would make by selling their goods. Otherwise they would have accepted any sort of valuable material as payment, knowing they could use it themselves or convert it into dwarven coins by reselling it later.