Rurouni Kenshin: Aoshi just because he manages to keep a straight face in a fight, also the fact he just kicks ass in general.

GetBackers: Amano Ginji because he rules, hes funny as hell with Akabane and in all around context.

Hunter X Hunter: Hisoka + Killua, Hisoka is creepy as F**K! I mean, he gets off over Gon and Danchou, if thats not weird what is. And Killua because hes cocky as hell and totally kicks ass.

Yu Yu Hakusho: Hiei cause hes a pissy little fire demon.

DBZ: Vegeta because of his arrogance and humour.

GunGrave: Brandon Heat as he kicks ass with a gun.

Trigun: Vash The Stampede because hes one of the funniest anime characters ever.

Ghost In The Shell - Stand Alone Complex: Tachikomas cause they are the greatest robots EVER with their little voices and funny as hell attitude.