That form is from Tekken 5, he's the sub boss before the last one which is his grand father (Jinpachi). Devil Jin fights like Tekken 3 Jin (Kazama style), there is also normal Jin who plays like the Tekken 4 style (Karate). In the game, he has both Angel and Devil in him depending on what triggers which, unfortunatly the presense of his evil Grandfather made him turn pure Devil hence ala Devil Jin.

Ok, in the pic u can kinda ignore the bottom half of him and concentrate more on the top half. I think it looks like Sasuke then.