The problem is that she represent the old, oppressive royal family that was thrown out. Although she might be the single "different" member in the eyes of those who know more, in the eyes of the mobs she would just be a member of the hated family. So, if she becomes the wife of the new king, wouldn't the masses fear that nothing will change as the old royals found a way to keep themselves afloat? Of course Souma's charisma and new methods have already proven themselves, but I still think Roroa might not be an advantage in Amidonia, under the current situation.